太湖五里湖水体悬浮物中水溶性有机质(WSOM)的荧光光谱组分鉴别及其与氮形态的关系   总被引：2，自引：2，他引：0  

张博  王书航  姜霞  黄晓峰  王雯雯 《湖泊科学》2018,30(1):102-111

采用三维荧光光谱-平行因子法(EEMs-PARAFAC)分析太湖五里湖水体悬浮物中水溶性有机质(WSOM)的荧光光谱特征,研究其组分类型、分布规律以及来源,进一步探讨悬浮物中水溶性有机氮和无机氮含量与WSOM荧光组分之间的关系.结果表明,悬浮物中WSOM荧光组分主要由2个类腐殖质(C1、C2)和1个类色氨酸类蛋白质(C3)组成.总荧光强度在57.56~200.01 R.U./g之间,平均为115.42 R.U./g,其中C1、C2、C3的相对比例分别为35.55%、34.05%和30.40%;空间上由西向东逐渐增强,东五里湖高于西五里湖,沿岸区高于湖心区.荧光指数和生物源指数变化范围分别在1.48~2.34和0.65~0.87之间,反映了悬浮物中WSOM主要来源于微生物、藻类的自生生物源.多元回归统计分析结果表明,悬浮物WSOM与氮元素的迁移转化密切相关,且有机氮与WSOM荧光组分的相关系数大于无机氮.  相似文献   

滇池沉水植物生长过程对间隙水氮、磷时空变化的影响   总被引：4，自引：0，他引：4  

张云  王圣瑞  段昌群  焦立新  王一茹  高秋生 《湖泊科学》2018,30(2):314-325

2015年6-10月通过原位采集滇池沉水植物分布区和无植物对照区柱状沉积物间隙水,分析其溶解性总氮(DTN)和溶解性总磷(DTP)、溶解性无机氮(DIN)和溶解性无机磷(DIP)及溶解性有机氮(DON)和溶解性有机磷(DOP)浓度的时空变化,探讨沉水植物分布对间隙水氮、磷浓度、形态贡献及氮磷比的影响.结果表明:滇池沉水植物生长过程显著影响间隙水氮、磷浓度.与无植物对照区相比,沉水植物生长过程对间隙水氮浓度的削减主要发生在6、8月,而对间隙水磷浓度的削减主要发生在7月,反映了沉水植物对氮、磷两种元素的生物地球化学循环作用机制不同;间隙水氮形态贡献受季节性影响较大,6-7月以DON贡献为主,沉水植物分布区和无植物对照区分别达到61%和84%;而8-10月以DIN贡献为主,沉水植物分布区和无植物对照区分别为76%和75%;沉水植物分布区磷形态贡献随季节波动变化,沉水植物分布区以DOP贡献为主(63%),无植物对照区以DIP贡献为主(62%);沉水植物生长对沉积物间隙水各形态氮磷比影响显著.沉水植物生长显著增加间隙水DTN/DTP比,尤其是DIN/DIP比,相反降低DON/DOP比.沉水植物对间隙水氮、磷吸收及转化过程改变了沉积物氮、磷释放机制,从而影响上覆水氮、磷组成及氮磷比,很可能会影响到浮游植物生长及藻类水华过程,这对于湖泊水质管理具有重要意义.  相似文献   

东洞庭湖沉积物覆水后磷形态变化及其释放量   总被引：4，自引：1，他引：3  

王婷  王坤  姜霞 《湖泊科学》2018,30(4):937-947

研究干燥覆水后低流速条件下东洞庭湖沉积物中磷的形态变化及释放量,可以为轻度富营养化湖泊中磷的生物地球化学循环提供基础数据,为季节性湖泊內源营养盐的迁移转化规律研究、內源营养盐的释放风险评价提供理论依据.本文采集处于干湿交替状态的东洞庭湖表层沉积物,利用室内模拟装置,研究风干沉积物低流速条件下覆水后沉积物及上覆水中磷的形态变化.结果表明,低流速覆水后东洞庭湖沉积物中的磷向上覆水及大气中迁移释放,上覆水中磷的释放量随覆水时长增大,释放速率随覆水时长减小,上覆水流速和磷释放量相关性显著.上覆水循环过程中释放到上覆水中的溶解态有机磷比溶解态活性磷更容易吸附于颗粒物而转化为颗粒态磷.覆水后沉积物中各形态有机磷、无机磷及磷的生物有效性均发生转变,覆水初期沉积物中无机磷向有机磷转化,磷的生物可利用性增大;上覆水循环过程中有机磷向无机磷转化,磷的生物可利用性减小;覆水后沉积物的无机磷的主要组分由铝磷转变为铁磷,有机磷的主要组分有从中活性有机磷向活性有机磷转变的趋势.  相似文献   

Co-productive governance: A relational framework for adaptive governance     

《Global Environmental Change》2015

Adaptive governance focuses our attention on the relationships between science and management, whereby the so-called ‘gaps’ between these groups are seen to hinder effective adaptive responses to biophysical change. Yet the relationships between science and governance, knowledge and action, remain under theorized in discussions of adaptive governance, which largely focuses on abstract design principles or preferred institutional arrangements. In contrast, the metaphor of co-production highlights the social and political processes through which science, policy, and practice co-evolve. Co-production is invoked as a normative goal (Mitchell et al., 2004) and analytical lens (Jasanoff, 2004a, Jasanoff, 2004b), both of which provide useful insight into the processes underpinning adaptive governance. This paper builds on and integrates these disparate views to reconceptualize adaptive governance as a process of co-production. I outline an alternative conceptual framing, ‘co-productive governance’, that articulates the context, knowledge, process, and vision of governance. I explore these ideas through two cases of connectivity conservation, which draws on conservation science to promote collaborative cross-scale governance. This analysis highlights the ways in which the different contexts of these cases produced very different framings and responses to the same propositions of science and governance. Drawing on theoretical and empirical material, co-productive governance moves beyond long standing debates that institutions can be rationally crafted or must emerge from context resituate adaptive governance in a more critical and contextualized space. This reframing focuses on the process of governance through an explicit consideration of how normative considerations shape the interactions between knowledge and power, science and governance.  相似文献   

金属的理化性质和地壳丰度的相互关系初步研究     

刘静  穆云松  王颖  陈程  朱元荣  吴丰昌 《矿物岩石地球化学通报》2015,(2):419-425

本文旨在探讨金属元素的理化性质和其地壳丰度(CA)的分布规律。利用相关性分析和集对分析研究了金属的理化性质和其地壳丰度的关系。结果表明,金属元素21种理化参数与地壳丰度之间均有不同程度的相关性。其中10种理化参数和地壳丰度显著相关(P≤0.05),包括共价指数(X2mr)、原子密度(ρ)、原子序数(AN)、原子量(AW)、有效核电荷(Z*)、电负性(Xm)、软指数(σp)、电子亲和能(EA)、极化力(Z*2/r)和电化学势(ΔE0)。集对分析进一步表明:X2mr,ρ,Z*和Xm与log(CA)之间趋同性较好,支持了相关分析的结论。研究结果暗示金属的理化性质与地壳丰度之间存在密切的内在关系,这为地球演化成因、元素丰度演变规律提供了新证据,对岩石、矿产资源开发和利用等有重要意义。  相似文献   

Organochlorine pesticides in soil and air at and around a compound contaminated site: vertical distribution,soil–air exchange and risk evaluation     

Fang  Yanyan  Nie  Zhiqiang  Die  Qingqi  Tian  Yajun  Liu  Feng  He  Jie  Huang  Qifei 《Stochastic Environmental Research and Risk Assessment (SERRA)》2018,32(4):1179-1188

The control of soil pollution in China has become an issue, and in this study, a compound contaminated site was selected and focus on the site and its nearby environment, organochlorine pesticides (OCPs) were investigated in both soil (top and deep soil) and air samples. The main pollutants in top soils at site are dichlorodiphenyltrichloroethane (DDTs, 0.05–104 mg/kg d.w., avg: 14.5 mg/kg d.w.) and hexachlorobenzene (HCB, 0.02–4.85 mg/kg d.w., avg: 0.72 mg/kg d.w.) which is in accordance with its production history. As for the deep soils, ΣOCPs at site were found concentrated at workshops especially the technical pesticide workshop (5.29–22.1 mg/kg d.w., avg: 9.15 mg/kg d.w.) and the history DDTs’ workshop (4.00–64.8 mg/kg d.w., avg: 20.4 mg/kg d.w). Around site, OCPs were mainly concentrated at layers of −20 cm and the −40 cm and decreased with distance being far away, at 5000 m, the ΣOCPs was comparable with normal agriculture soil (22.1−91.4 ng/g d.w., avg: 55.4 ng/g d.w.). ΣOCPs in the air samples ranged 64.6–823 ng/m³ (avg: 459 ng/m³) at site and 9.93–176 ng/m³ (avg: 50.8 ng/m³) around site which are all dominated with DDTs and HCHs. Soil–air exchange fugacity was calculated to judge the transportation of the OCPs and the results showed soils at the site and its nearby areas (within 5000 m) are releasing most of the OCPs into air, and accordingly through evaluation, inhalation was found to be the major source for human health risk, which is a great threat to the workers at site and the nearby residents.

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Using conservation as a tool to resolve conflict: Establishing the Piran–Savudrija international Marine Peace Park     

《Marine Policy》2013

Border disputes between neighbouring States are a regular occurrence and have the potential to undermine relations at national, regional, local and even individual level. In this instance the conflict over Piran Bay in the Northern Adriatic Sea has led to conflict between the neighbouring States of Croatia and Slovenia. The lack of resolution of this conflict resulted in Croatia being delayed in its accession into the European Union (EU). The border dispute remains unresolved and will go to international arbitration in 2013. Yet it is unlikely that arbitration will provide a solution agreeable to all stakeholders. It is likely that residual feelings of injustice will remain, especially at local level. Analysis of the political context of the dispute and recognition of the biological importance of the region has led to opportunity to combine politics and biological conservation to establish an International Marine Peace Park (IMPP) as a potential mitigation measure to help resolve the conflict. This initiative aims to develop regional ownership over a shared marine space linking the local communities of Slovenia and Croatia that co-habit the adjacent Istrian peninsula. The area of the proposed Piran–Savudrija IMPP hosts numerous habitat types and species which are representative of the region and are of international and national conservation importance. The policies and opportunities associated with EU accession provide the potential political, economic and environmental frameworks to develop a regional agency or a bi-national steering committee for the management of the area. This could allow local communities to develop equitable management and restore good relations while preserving an important regionally representative marine area.  相似文献   

Antimony in the environment: a review focused on natural waters: I. Occurrence     

《Earth》2002,57(1-2):125-176

Antimony is ubiquitously present in the environment as a result of natural processes and human activities. It exists mainly as Sb(III) and Sb(V) in environmental, biological and geochemical samples. Antimony and its compounds are considered to be priority pollutants interest by the USEPA and the EU. In this first review paper on antimony occurrence in natural waters, 420 papers on freshwaters, marine waters, estuaries, soils, and sediments have been reviewed. All data are quoted from the original sources. Typical concentrations of total dissolved antimony are usually less than 1.0 μg/l in non-polluted waters. When redox speciation determinations are performed, most studies report the dominance of Sb(V) under oxic conditions. However, the presence of significant proportions of Sb(III) is sometimes detected. This is in contrast with thermodynamic equilibrium predictions and discrepancies are often attributed to biological activity or kinetic effects but proofs are lacking. Similarly, the existence of Sb(V), although not thermodynamically predicted, is often reported under anoxic conditions. Low concentrations of methylated antimony species are mentioned in a few studies. Antimony is not considered to be a highly reactive element in oceans, with concentrations of the order of 200 ng/l. In estuarine waters, both conservative and non-conservative behaviours are reported depending on the estuaries' characteristics. Elevated concentrations of antimony in soils and sediments are either related to anthropogenic sources or associated with high arsenic concentrations in sulfidic ores. Antimony appears to be highly unreactive in soils. Low accumulation factors are reported in algae. Airborne supply of antimony to aquatic and terrestrial systems seems to be important in systems far from direct pollution sources. However, the limited available data do not allow firm conclusions to be drawn on the reactivity and cycling of the element in natural systems and a list of research priorities is given.  相似文献   

Identification and emission factors of molecular tracers in organic aerosols from biomass burning Part 1. Temperate climate conifers     

《Applied Geochemistry》2001,16(13):1513-1544

Smoke particulate matter from conifers subjected to controlled burning, both under smoldering and flaming conditions, was sampled by high volume air filtration on precleaned quartz fiber filters. The filtered particles were extracted with dichloromethane and the crude extracts were methylated for separation by thin layer chromatography into hydrocarbon, carbonyl, carboxylic acid ester and polar fractions. Then, the total extract and individual fractions were analyzed by gas chromatography and gas chromatography–mass spectrometry. The major organic components directly emitted in smoke particles were straight chain aliphatic compounds from vegetation wax and diterpenoid acids (biomarkers) from resin. The major natural products altered by combustion included derivatives from phenolic (lignin) and monosaccharide (cellulose) biopolymers and oxygenated and aromatic products from diterpenoids. Other biomarkers present as minor components included phytosterols, both the natural and altered products, and unaltered high molecular weight wax esters. Polycyclic aromatic hydrocarbons (PAH) were also present, however, only as minor constituents. Although the concentrations of organic compounds in smoke aerosols are highly variable and dependent on combustion temperature, the biomarkers and their combustion alteration products are source specific. The major components are adsorbed or trapped on particulate matter and thus may be utilized as molecular tracers in the atmosphere for determining fuel type and source contributions from biomass burning.  相似文献   

Tropospheric Wet Refractivity Tomography Based on the BeiDou Satellite System简     

WANG Xiaoying  WANG Xianliang  DAI Ziqiang  KE Fuyang  CAO Yunchang  WANG Feifei  and SONG Lianchun 《大气科学进展》2014,31(2):355-362

This paper presents a novel approach for assessing the precision of the wet refractivity field using BDS （BeiDou navigation satellite system） simulations only,GPS,and BDS＋GPS for the Shenzhen and Hongkong GNSS network.The simulations are carried out by adding artificial noise to a real observation dataset.Instead of using the δ and σ parameters computed from slant wet delay,as in previous studies,we employ the Bias and RMS parameters,computed from the tomography results of total voxels,in order to obtain a more direct and comprehensive evaluation of the precision of the refractivity field determination.The results show that：（1） the precision of tropospheric wet refractivity estimated using BDS alone （only 9 satellites used） is basically comparable to that of GPS; （2） BDS＋GPS （as of current operation） may not be able to significantly improve the data＇s spatial density for the application of refractivity tomography; and （3） any slight increase in the precision of refractivity tomography,particularly in the lower atmosphere,bears great significance for any applications dependent on the Chinese operational meteorological service.  相似文献